Berylloles and Alumoles: Highly Unsaturated Antiaromatics at the Frontiers of Metallacyclopentadiene Chemistry

铍和铝分子：金属环戊二烯化学前沿的高度不饱和抗芳烃

• 批准号: 446663029
• 负责人: Professor Dr. Holger Braunschweig
• 金额: --
• 依托单位: Institut für Anorganische Chemie
• 依托单位国家: 德国
• 项目类别: Research Grants
• 资助国家: 德国
• 项目状态: 未结题
• 来源: https://gepris.dfg.de/gepris/projekt/446663029?language=en
• 关键词: Berylloles; Alumoles; Highly; Unsaturated; Antiaromatics

The heterocyclopentadiene or metallocyclopentadiene ring system (cyclo-EC4R4 or -MC4R4) is an archetypal molecular architecture and now exist with elements from all corners of the periodic table. Our extensive research on boroles (i.e. boracyclopentadienes) has recently sparked our interest in analogues featuring elements neighbouring boron in the periodic table, namely beryllium and aluminium. These molecules, named berylloles and alumoles, are electronically and coordinatively unsaturated, antiaromatic, and highly reactive, leading to a number of interesting preliminary results. This project will target these two fascinating systems, their elaboration, and the full exploitation of their very promising reactivity in a number of different directions.

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