New Synthetic Routes to the Immobilisation of Mixed Valence Transition Metal Complexes on Conducting Metal Oxides

混合价过渡金属配合物在导电金属氧化物上固定化的新合成路线

• 批准号: LX0560194
• 负责人: Prof Paul Bernhardt
• 金额: $ 1.35万
• 依托单位: The University of Queensland
• 依托单位国家: 澳大利亚
• 项目类别: Linkage - International
• 财政年份: 2005
• 资助国家: 澳大利亚
• 起止时间: 2005-01-01 至 2006-12-31
• 项目状态: 已结题
• 来源: https://dataportal.arc.gov.au/RGS/Web/Grants/LX0560194
• 关键词: New; Synthetic; Routes; Immobilisation; Mixed

Highly coloured, electrochemically active transition metal dyes may find application electrochromic devices, where they may switch between contrasting coloured forms through a simple redox reaction. A prerequisite is that the dye be immobilised onto a solid conducting support whilst preserving the electrochemical and optical properties of the dye found in solution. This project tackles this problem through a combination of organic and inorganic synthesis to develop new electrochromic dyes that may be attached to mesoporous titania.

高度着色的电化学活性过渡金属染料可以应用于电致变色装置，其中它们可以通过简单的氧化还原反应在对比色形式之间切换。一个先决条件是染料被固定在固体导电载体上，同时保持溶液中染料的电化学和光学性质。该项目通过有机和无机合成的组合来解决这个问题，以开发可能附着到介孔二氧化钛上的新的电致变色染料。