Tellurium-based reagents and materials

碲基试剂和材料

• 批准号: 479116-2015
• 负责人: Seferos, Dwight
• 金额: $ 10.93万
• 依托单位: University of Toronto
• 依托单位国家: 加拿大
• 项目类别: Strategic Projects - Group
• 财政年份: 2016
• 资助国家: 加拿大
• 起止时间: 2016-01-01 至 2017-12-31
• 项目状态: 已结题
• 来源: https://www.nserc-crsng.gc.ca/ase-oro/Details-Detailles_eng.asp?id=599879
• 关键词: Tellurium; based; reagents; materials

Frustrated Lewis pair (FLP) chemistry is a new paradigm for synthetic and catalytic chemistry. Te- containing heterocycles have lead to the development of new classes of highly desirable photo-active and electro-active materials. These areas have been pioneered by both Stephan and Seferos. In this proposal, the diverse advances made by Stephan and Seferos are merged to target facile and new synthetic routes to unprecedented Te-based molecules and materials. The synthesis, characterization, and properties of these compounds will be determined. We are specifically interested in using these compounds as reagents. Additionally, the team plans to extend Te-Based FLP chemistry to polymers, leading to new classes of and photo-addressable and electronic materials.

阻挫刘易斯对（FLP）化学是合成化学和催化化学的新范式。含Te杂环已经导致开发了新类别的高度期望的光活性和电活性材料。这些领域都是由Stephan和Seferos开创的。在这项提案中，Stephan和Seferos所取得的各种进展被合并，以针对前所未有的基于Te的分子和材料的简单和新的合成路线。将确定这些化合物的合成、表征和性质。我们特别感兴趣的是使用这些化合物作为试剂。此外，该团队计划将基于Te的FLP化学扩展到聚合物，从而产生新的光寻址和电子材料。