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Berylloles and Alumoles: Highly Unsaturated Antiaromatics at the Frontiers of Metallacyclopentadiene Chemistry

Berylloles and Alumoles: Highly Unsaturated Antiaromatics at the Frontiers of Metallacyclopentadiene Chemistry
铍和铝分子:金属环戊二烯化学前沿的高度不饱和抗芳烃
批准号:
446663029
负责人:
Professor Dr. Holger Braunschweig
金额:
$0.0万
依托单位国家:
德国
项目类别:
Research Grants
财政年份:
--
资助国家:
德国
项目状态:
未结题
起止时间:

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中文摘要
翻译
杂环戊二烯或金属环戊二烯环体系(环- ec4r4或-MC4R4)是一种典型的分子结构,现在存在于元素周期表的各个角落。我们对硼(即硼环戊二烯)的广泛研究最近激发了我们对元素周期表中邻近硼元素的类似物的兴趣,即铍和铝。这些分子被命名为绿柱石和铝孔,它们是电子和配位不饱和的,反芳香的,高活性的,导致了许多有趣的初步结果。这个项目将针对这两个迷人的系统,它们的细化,并在许多不同的方向上充分利用它们非常有前途的反应性。
英文摘要
The heterocyclopentadiene or metallocyclopentadiene ring system (cyclo-EC4R4 or -MC4R4) is an archetypal molecular architecture and now exist with elements from all corners of the periodic table. Our extensive research on boroles (i.e. boracyclopentadienes) has recently sparked our interest in analogues featuring elements neighbouring boron in the periodic table, namely beryllium and aluminium. These molecules, named berylloles and alumoles, are electronically and coordinatively unsaturated, antiaromatic, and highly reactive, leading to a number of interesting preliminary results. This project will target these two fascinating systems, their elaboration, and the full exploitation of their very promising reactivity in a number of different directions.
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Lewis Base Activation of Di- and Tetrahalodiboranes for Organic and Inorganic Chemistry
  • 批准号:
    396769488
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2018
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
Electron-Rich Monovalent Boron: A Platform for Metal Mimicry
  • 批准号:
    325229020
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2017
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
Photophysical Engineering of Transition Metal pi-Diborene and -Diboryne Complexes
  • 批准号:
    271723449
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2015
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
Transition-Metal-Catalysed Borane Dehydrocoupling and its Mechanistic Implications
  • 批准号:
    242159665
  • 项目类别:
    Research Grants
  • 资助金额:
    $0.0万
  • 财政年份:
    2013
  • 负责人:
    Professor Dr. Holger Braunschweig
  • 依托单位:
海外基金