Berylloles and Alumoles: Highly Unsaturated Antiaromatics at the Frontiers of Metallacyclopentadiene Chemistry
Berylloles and Alumoles: Highly Unsaturated Antiaromatics at the Frontiers of Metallacyclopentadiene Chemistry
批准号:
446663029
负责人:
Professor Dr. Holger Braunschweig
金额:
$0.0万
依托单位国家:
德国
项目类别:
Research Grants
财政年份:
--
资助国家:
德国
项目状态:
未结题
起止时间:
中文摘要
杂环戊二烯或金属环戊二烯环体系(环- ec4r4或-MC4R4)是一种典型的分子结构,现在存在于元素周期表的各个角落。我们对硼(即硼环戊二烯)的广泛研究最近激发了我们对元素周期表中邻近硼元素的类似物的兴趣,即铍和铝。这些分子被命名为绿柱石和铝孔,它们是电子和配位不饱和的,反芳香的,高活性的,导致了许多有趣的初步结果。这个项目将针对这两个迷人的系统,它们的细化,并在许多不同的方向上充分利用它们非常有前途的反应性。
英文摘要
The heterocyclopentadiene or metallocyclopentadiene ring system (cyclo-EC4R4 or -MC4R4) is an archetypal molecular architecture and now exist with elements from all corners of the periodic table. Our extensive research on boroles (i.e. boracyclopentadienes) has recently sparked our interest in analogues featuring elements neighbouring boron in the periodic table, namely beryllium and aluminium. These molecules, named berylloles and alumoles, are electronically and coordinatively unsaturated, antiaromatic, and highly reactive, leading to a number of interesting preliminary results. This project will target these two fascinating systems, their elaboration, and the full exploitation of their very promising reactivity in a number of different directions.
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Lewis Base Activation of Di- and Tetrahalodiboranes for Organic and Inorganic Chemistry
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批准号:396769488
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2018
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Electron-Rich Monovalent Boron: A Platform for Metal Mimicry
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批准号:325229020
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2017
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Photophysical Engineering of Transition Metal pi-Diborene and -Diboryne Complexes
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批准号:271723449
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2015
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Transition-Metal-Catalysed Borane Dehydrocoupling and its Mechanistic Implications
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批准号:242159665
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2013
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Metal-Mediated Cyclisation of Iminoboranes: Organometallic Chemistry and Functional BN-Isosteres
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批准号:238305216
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2013
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Reduction of Mono- and Diboranes(4)
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批准号:221758282
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2012
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Chemistry of Free Boroles
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批准号:186904585
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2010
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Dynamic Metal-to-Element Dative Bonds and their Applications Beyond the Molecule
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批准号:192178519
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2010
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Boryl- und Borylenkomplexe von Palladium und Platin
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批准号:24798567
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2006
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Electron density distribution in borylene complexes
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批准号:5449393
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项目类别:Priority Programmes
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资助金额:$0.0万
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财政年份:2005
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Synthese, Struktur und Reaktivität von Bor-verbrückten Metallocenophanen und verwandten Verbindungen
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批准号:5451600
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2005
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Synthese, Struktur und Reaktivität von Borylenkomplexen
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批准号:5428093
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:2004
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Synthese, Struktur und Reaktionen von Übergangsmetallboryl- und -borylenkomplexen
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批准号:5308072
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:1996
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Subvalent aluminum: versatile reagents for the generation of homo- and heterodiatomic Al-E linkages
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批准号:450280494
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
The Chemistry of Borylenes and their Products: Reactive Superdonors and Superambiphiles
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批准号:396285167
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Boraheterocumulenes: Versatile Building Blocks for the Construction of B–E Multiple Bond Species and B,E-Doped Heterocycles
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批准号:530906430
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
This proposal aims to prepare the first polymers based on chains of boron atoms, and to utilise their unique properties
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批准号:390765178
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项目类别:Reinhart Koselleck Projects
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Exploiting Transition-Metal-Free Nitrogen Activation for Organic and Inorganic Synthesis
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批准号:494871290
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Neutral diborabenzenes – highly electron-rich systems for classical arene-type reactivity, bond activation, and catalysis
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批准号:452730967
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
Diborenium and Diborynium Cations: Combining Hypovalency, Multiple Bonding, Positive Charge and Unpaired Electrons
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批准号:469029582
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项目类别:Research Grants
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资助金额:$0.0万
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财政年份:--
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负责人:Professor Dr. Holger Braunschweig
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依托单位:
海外基金