Hypermolecular Photochirogenesis

在本研究中，我们首先阐明了无机、有机和生物超分子体系的手性、客体亲和和光致氮性能，然后开发了各种新的手性超分子组合体系，并建立了多维控制策略，将其联合应用于多种光致氮反应，最终实现了高达99%的前所未有的高光产率。这一直是研究这一科学领域的研究人员的梦想。在光化学、超分子化学和不对称合成的交叉领域，我们发表了97篇原创论文和评论，并出版了第一本专著，以提高其在科学界的知名度。

In this study, we first elucidated the chiral properties, guest affinities, and photochirogenic performances of inorganic, organic, and biological supramolecular systems, and then developed various novel chiral supramolecular combination systems and established the multidimensional control strategies, which were jointly applied to several photochirogenic reactions to ultimately achieve unprecedentedly high optical yields of up to 99%, which has been a sort of dream for researchers working in this area of science. We published 97 original papers and reviews as well as the first book on this new interdisciplinary area at the intersection of photochemistry, supramolecular chemistry, and asymmetric synthesis to enhance its visibility in science community.