Materials World Network: An International Collaborative Educational and Research Program in the Study of Mixed Glass Former Phenomena in Materials

材料世界网络：研究材料中混合玻璃前体现象的国际合作教育和研究计划

• 批准号: 0710564
• 负责人: Steve Martin
• 金额: $ 100.9万
• 依托单位: Iowa State University
• 依托单位国家: 美国
• 项目类别: Continuing Grant
• 财政年份: 2007
• 资助国家: 美国
• 起止时间: 2007-08-15 至 2013-07-31
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=0710564&HistoricalAwards=false
• 关键词: Materials; World; Network; International; Collaborative

This Materials World Network (MWN) project examines the universally observed Mixed Glass Former Effect (MGFE) where independent of the mobile cation, independent of the two glass formers used, independent of whether the system is all-oxide, all-sulfide, or even mixed oxy-sulfide, and independent of the over-all mobile cation concentration, the ionic conductivities of Mixed Glass Former (MGF) glasses are always higher than that of the two parent binary glasses at the same level of mobile cation concentration. With the recent and well known problems of liquid polymer electrolytes in millions of lithium batteries, there is a renewed interest in solid electrolytes for lithium batteries. Such MGF glasses make ideal candidates due to their anomalously high ionic conductivities and other advantageous properties brought about by the mixing of the glass formers. However, before wide spread application of these electrolytes can be implemented, a detailed understanding of the MGFE must be developed first. For this reason, the intellectual merit of this project is that an international research team has been assembled to form a Materials World Network of research capability from among three universities in the US and three universities in Europe. Researchers in the US are preparing the glasses and measuring the composition dependence of the conductivity and examining short range structures through vibrational spectroscopy (Martin-Iowa State University). Both short and intermediate range structures of the glasses are being examined using high resolution x-ray diffraction (Petkov-Central Michigan University) and tracer diffusion coefficients are being measured (Dieckmann-Cornell). The European collaborators are providing complimentary neutron diffraction (Brjesson-Chalmers Institute of Technology, Sweden) and nuclear magnetic resonance (Eckert- Westfalische Wilhems-Mnster University, Germany) data to extend the detail of structural studies. European collaborators are also providing theoretical modeling and simulation of both the ionic conductivity and structure of the glasses (Maass- Technical University Ilmenau, Germany) and for theoretical modeling of the ion dynamic processes that are apparently greatly magnified in MGFE glasses (Funke-Mnster U., Germany). The project synergistically combines both structural and dynamical studies of the MGFE in oxide, sulfide, and oxy-sulfide glasses to determine the nature, extent, and role of the favorable structural features of MGFE glasses. The broader impacts of this project are to use new modalities of international collaboration to provide young researchers new education experiences to broaden and deepen their research abilities, and to expand and develop their professional and international awareness to enhance their global citizenry. This is achieved by providing students with unique extended collaborative research and education experiences in the European collaborators' laboratories, and by having them host European students in the US to create professional linkages and experiences throughout this program. Deep collaborations among other MWN projects in similar countries are developed to leverage learning among the MWNs and speed up the development of best practices for such international collaborations. Collaboration is also established with local 2- and 4- year colleges to draw undergraduates, especially women and minorities, to the program to foster new 4 year graduates and new graduate students. The framework of the MWN is also used to develop new modalities of distance utilization of research equipment through common operating systems and high-speed internet connections, and to develop sustainable collaborations among the partners of the program that foster long term progress on research.This award is co-funded with the Office of International Science and Engineering.

该材料世界网络（MWN）项目检查了普遍观察到的混合玻璃形成剂效应（MGFE），其中独立于移动的阳离子，独立于使用的两种玻璃形成剂，独立于系统是否为全氧化物，全硫化物或甚至混合氧硫化物，并且独立于整体移动的阳离子浓度，在相同的移动的阳离子浓度水平下，混合玻璃形成体（MGF）玻璃的离子电导率总是高于两种母体二元玻璃。随着最近在数百万锂电池中的液体聚合物电解质的众所周知的问题，对用于锂电池的固体电解质重新产生了兴趣。这种MGF玻璃由于其极高的离子电导率和由玻璃形成剂的混合所带来的其它有利性质而成为理想的候选物。然而，在这些电解质的广泛应用可以实施之前，必须首先开发对MGFE的详细理解。因此，该项目的智力价值在于，一个国际研究团队已经聚集在美国三所大学和欧洲三所大学之间，形成了一个材料世界研究能力网络。美国的研究人员正在准备玻璃，测量电导率的成分依赖性，并通过振动光谱检查短程结构（马丁-爱荷华州立大学）。使用高分辨率X射线衍射（Petkov-Central Michigan University）检查玻璃的短程和中程结构，并测量示踪剂扩散系数（Dieckmann-Cornell）。欧洲合作者正在提供免费的中子衍射（Brjesson-Chalmers Institute of Technology，瑞典）和核磁共振（Eckert- Westfalische Wilhems-Mnster University，德国）数据，以扩展结构研究的细节。欧洲合作者还提供了玻璃的离子电导率和结构的理论建模和模拟（Maass-Technical University Ilmenau，德国）以及在MGFE玻璃中明显大大放大的离子动力学过程的理论建模（Funke-Mnster U.，德国）。该项目协同结合了氧化物，硫化物和氧硫化物玻璃中MGFE的结构和动力学研究，以确定MGFE玻璃有利结构特征的性质，程度和作用。该项目的更广泛影响是利用国际合作的新模式，为年轻研究人员提供新的教育经验，以扩大和深化他们的研究能力，并扩大和发展他们的专业和国际意识，以提高他们的全球公民身份。这是通过在欧洲合作者的实验室为学生提供独特的扩展合作研究和教育经验，并让他们在美国接待欧洲学生，在整个项目中创造专业联系和经验来实现的。在类似国家的其他MWN项目之间开展深入合作，以利用MWN之间的学习，并加快为此类国际合作制定最佳实践。还与当地2年制和4年制大学建立了合作关系，吸引本科生，特别是妇女和少数民族，参加该方案，以培养新的4年制毕业生和新的研究生。MWN的框架还用于开发通过通用操作系统和高速互联网连接远程利用研究设备的新模式，并在该计划的合作伙伴之间建立可持续的合作关系，以促进研究的长期进展。该奖项与国际科学与工程办公室共同资助。