Hydrogen in the Ultrawide Bandgap Semiconductor beta-Ga203

超宽带隙半导体 beta-Ga2O3 中的氢

• 批准号: 1901563
• 负责人: Michael Stavola
• 金额: $ 33.67万
• 依托单位: Lehigh University
• 依托单位国家: 美国
• 项目类别: Standard Grant
• 财政年份: 2019
• 资助国家: 美国
• 起止时间: 2019-07-01 至 2024-06-30
• 项目状态: 已结题
• 来源: https://www.nsf.gov/awardsearch/showAward?AWD_ID=1901563&HistoricalAwards=false
• 关键词: Hydrogen; Ultrawide; Bandgap; Semiconductor; beta

Nontechnical description: Semiconductors with bandgaps larger than those of gallium nitride and silicon carbide are emerging as a new class of ultra-wide-bandgap electronic materials for high-power, deep-ultraviolet, and extreme-environment applications. Despite the tremendous potential of the ultra-wide-bandgap semiconductors for device applications, with orders of magnitude improvement over devices made from more conventional semiconductors, the fundamental underlying mechanisms of their electrical properties are poorly understood. This project is focused particularly on gallium oxide, a semiconducting oxide with a bandgap of 4.9 eV, that is an attractive candidate for high-power devices. In spite of its promising applications, gallium oxide remains underexplored, and the defects and impurities that affect its electrical properties remain controversial, opening exciting opportunities for fundamental research that impacts technology. Hydrogen impurities and their chemical reactions strongly affect the electronic properties of gallium oxide and are of particular interest in this project. Experimental studies of defects and impurities in gallium oxide provide an excellent opportunity for students to solve important problems in materials physics, igniting excitement that leads to a successful career in science and engineering. The recruiting of students from groups that are under-represented in physics is expanded in the present project.Technical description: This project is focused on experimental investigation of the hydrogen impurity in gallium oxide, a semiconducting oxide with an ultra-wide bandgap of 4.9 eV. Hydrogen is an important impurity in oxide semiconductors where it can give rise to n-type conductivity and can also compensate deep acceptors. While there are a few theoretical predictions for the properties of hydrogen in gallium oxide, the research in this area is in its infancy. Gallium oxide promises to show new behaviors and to reveal new defect physics. The research involves a complementary set of experimental methods, aiming to determine how hydrogen impurities affect the electronic properties of gallium oxide and to test the theoretical predictions. For example, the combination of vibrational spectroscopy with free-carrier absorption provides a powerful strategy for studying hydrogen centers that relates specific defects with the conductivity they cause. Furthermore, the interactions of hydrogen with other defects such as gallium vacancy are investigated to probe the passivation of these deep acceptors by hydrogen. The addition of Raman scattering and photo-thermal ionization spectroscopies provide access to additional types of hydrogen species that do not have infrared absorption lines (such as molecular hydrogen) but that, nonetheless, play an important role in defect reactions that affect the conductivity of gallium oxide and its thermal stability. The expected outcome of this research is fundamental understanding of which hydrogen centers are n-type dopants in gallium oxide and investigates how hydrogen interacts with other defects that also affect electronic properties. The fundamental science of these defects and their reactions needs to be understood so that the conductivity of gallium oxide can be reliably controlled and engineered.This award reflects NSF's statutory mission and has been deemed worthy of support through evaluation using the Foundation's intellectual merit and broader impacts review criteria.

非技术性描述：具有比氮化镓和碳化硅更大的带隙的半导体正在成为一类新的超宽带隙电子材料，用于高功率，深紫外和极端环境应用。尽管超宽带隙半导体在器件应用方面具有巨大的潜力，与由更传统的半导体制成的器件相比有了几个数量级的改进，但对其电学特性的基本机制却知之甚少。该项目特别关注氧化镓，这是一种带隙为4.9 eV的半导体氧化物，是高功率器件的有吸引力的候选者。尽管氧化镓有着广阔的应用前景，但它的研究仍然不足，影响其电性能的缺陷和杂质仍然存在争议，为影响技术的基础研究提供了令人兴奋的机会。氢杂质及其化学反应强烈影响氧化镓的电子性质，在本项目中特别感兴趣。氧化镓中缺陷和杂质的实验研究为学生解决材料物理学中的重要问题提供了绝佳的机会，点燃了兴奋，导致科学和工程事业的成功。本项目扩大了对物理学方面代表性不足的群体的招生。技术说明：本项目的重点是对具有4.9 eV超宽带隙的半导体氧化物氧化镓中的氢杂质进行实验研究。氢是氧化物半导体中的重要杂质，在氧化物半导体中，氢可以产生n型导电性，并且还可以补偿深受主。虽然对氧化镓中氢的性质有一些理论预测，但这一领域的研究仍处于起步阶段。氧化镓有望显示新的行为，并揭示新的缺陷物理。该研究涉及一套补充的实验方法，旨在确定氢杂质如何影响氧化镓的电子特性，并测试理论预测。例如，振动光谱与自由载流子吸收的结合为研究氢中心提供了一个强大的策略，该策略将特定缺陷与它们引起的导电性联系起来。此外，氢与其他缺陷，如镓空位的相互作用进行了研究，以探讨这些深受主氢钝化。拉曼散射和光热电离光谱的增加提供了对不具有红外吸收线（例如分子氢）但在影响氧化镓的导电性及其热稳定性的缺陷反应中起重要作用的另外类型的氢物质的访问。这项研究的预期成果是从根本上了解哪些氢中心是氧化镓中的n型掺杂剂，并研究氢如何与其他影响电子特性的缺陷相互作用。需要了解这些缺陷及其反应的基础科学，以便能够可靠地控制和设计氧化镓的导电性。该奖项反映了NSF的法定使命，并通过使用基金会的知识价值和更广泛的影响审查标准进行评估，被认为值得支持。

项目成果

Trapping of multiple H atoms at the Ga(1) vacancy in β -Ga 2 O 3

在 β -Ga 2 O 3 中的 Ga(1) 空位处捕获多个 H 原子

• DOI: 10.1063/5.0024269
• 发表时间: 2020
• 期刊: Applied Physics Letters
• 影响因子: 4
• 作者: Fowler, W. Beall;Stavola, Michael;Qin, Ying;Weiser, Philip
• 通讯作者: Weiser, Philip

Impurity-hydrogen complexes in β-Ga2O3: Hydrogenation of shallow donors vs deep acceptors

• DOI: 10.1063/5.0080341
• 发表时间: 2022-01
• 期刊: Journal of Applied Physics
• 影响因子: 3.2
• 作者: Andrew Venzie;Amanda Portoff;E. C. P. Valenzuela;M. Stavola;W. Fowler;S. Pearton;E. Glaser

Editors’ Choice—Vibrational Properties of Oxygen-Hydrogen Centers in H + - and D + -Implanted Ga 2 O 3

编辑选择 – H 和 D 注入 Ga 2 O 3 中氧-氢中心的振动特性

• DOI: 10.1149/2162-8777/abd458
• 发表时间: 2020
• 期刊: ECS Journal of Solid State Science and Technology
• 影响因子: 2.2
• 作者: Portoff, Amanda;Venzie, Andrew;Qin, Ying;Stavola, Michael;Fowler, W. Beall;Pearton, Stephen J.
• 通讯作者: Pearton, Stephen J.

Determination of dielectric axes and transition moment directions in β-Ga 2 O 3 from the polarization dependence of vibrational spectra

根据振动光谱的偏振依赖性确定 β-Ga 2 O 3 中的介电轴和跃迁矩方向

• DOI: 10.1063/1.5142376
• 发表时间: 2020
• 期刊: Journal of Applied Physics
• 影响因子: 3.2
• 作者: Portoff, Amanda;Venzie, Andrew;Stavola, Michael;Fowler, W. Beall;Pearton, Stephen J.
• 通讯作者: Pearton, Stephen J.