Studies on Diversity and Synergy of Elements Directed toward Organic Synthesis
Studies on Diversity and Synergy of Elements Directed toward Organic Synthesis
批准号:
18105004
负责人:
NAKAMURA Eiichi
金额:
$71.8万
依托单位:
依托单位国家:
日本
项目类别:
Grant-in-Aid for Scientific Research (S)
财政年份:
2006
资助国家:
日本
项目状态:
已结题
起止时间:
2006 至 2009
中文摘要
本研究旨在以机理理解为导向的有机合成反应设计。因此,我们利用8-13族过渡金属的反应性和对它们的多金属合作关系的理解,开发了高效、立体选择性和官能团耐受的碳-碳键形成反应。我们充分利用元素多样性和多金属协同作用,开发了高效、高选择性和可持续性的合成方法,并将这些方法应用于有机电子器件新型π电子材料的制备。
英文摘要
The present research aimed at mechanistic understanding-driven design of organic synthetic reactions. Thus, we developed highly efficient, stereoselective and functional group-tolerant carbon-carbon bond formation reactions, taking advantage of the reactivity of group 8-13 transition metals and the understanding of their multimetallic cooperation. Fully utilizing element diversity and multimetallic cooperation, we developed synthetic methods of high efficiency, high selectivity and sustainability, and applied these methods for the creation of novelπ-electronic materials for organoelectronic devices.
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Stereoselective Synthesis of Trisubstituted E-lodoalkenes by Indium-Catalyzed syn-Addition of 1, 3-Dicarbonyl Compounds to 1-Iodoalkynes
铟催化 1, 3-二羰基化合物与 1-碘炔的顺式加成立体选择性合成三取代 E-碘代烯烃
DOI:
--
发表时间:
2008
期刊:
Organic Letters 10
影响因子:
--
作者:
[H. Tsuji, T. Fujimoto, K. Endo, M. Nakamura, E. Nakamura]
通讯作者:
E. Nakamura
Highly Efficient Nickel-Catalyzed Cross-Coupling of Aryl Carbamates and Phosphates with Grignard Reagents
镍催化芳基氨基甲酸酯和磷酸酯与格氏试剂的高效交叉偶联
DOI:
--
发表时间:
2007
期刊:
影响因子:
--
作者:
[松田広和, 吉戒直彦, 中村栄一]
通讯作者:
中村栄一
Synthesis of 3-Stannylbenzosilole and Its Applications in Preparing 2, 3-Disubstituted Benzosiloles
3-甲锡烷基苯并硅咯的合成及其在制备2, 3-二取代苯并硅咯中的应用
DOI:
--
发表时间:
2007
期刊:
影响因子:
--
作者:
[L. Ilies, H. Tsuji, M. Nakamura, E. Nakamura]
通讯作者:
E. Nakamura
DOI:
10.1021/ja800818b
发表时间:
2008-05-07
期刊:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
影响因子:
15
作者:
[Norinder, Jakob, Matsumoto, Arimasa, Nakamura, Eiichi]
通讯作者:
Nakamura, Eiichi
DOI:
10.1021/ja710408f
发表时间:
2008-04-02
期刊:
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
影响因子:
15
作者:
[Fujimoto, Taisuke, Endo, Kohei, Nakamura, Eiichi]
通讯作者:
Nakamura, Eiichi
共 31 条
Synthesis and Nano-organization of Organic Semiconductors for Efficient Photo-electronic Conversion
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批准号:22000008
-
项目类别:Grant-in-Aid for Specially Promoted Research
-
资助金额:$381.64万
-
财政年份:2010
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负责人:NAKAMURA Eiichi
-
依托单位:
BMP Signaling on Cartilage Repair Response in Full-thickness Articular Cartilage Defects
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批准号:12671425
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项目类别:Grant-in-Aid for Scientific Research (C)
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资助金额:$1.98万
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财政年份:2000
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负责人:NAKAMURA Eiichi
-
依托单位:
Highly reactive and selective olefin carbometalation
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批准号:08454196
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项目类别:Grant-in-Aid for Scientific Research (B)
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资助金额:$4.8万
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财政年份:1996
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负责人:NAKAMURA Eiichi
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依托单位:
Development of Five-membered Ring Forming Reactions by Control of Electronic States of Biradical
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批准号:05403015
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项目类别:Grant-in-Aid for General Scientific Research (A)
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资助金额:$22.46万
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财政年份:1993
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负责人:NAKAMURA Eiichi
-
依托单位:
Development of New Reactive Intermediates on the Basis of the Reactions of Functionalized Highly Strained Molecules
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批准号:63470013
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项目类别:Grant-in-Aid for General Scientific Research (B)
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资助金额:$4.61万
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财政年份:1988
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负责人:NAKAMURA Eiichi
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依托单位:
海外基金