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ANALYTICAL REAGENTS FROM DIHYDROFLUORESCEIN

ANALYTICAL REAGENTS FROM DIHYDROFLUORESCEIN
二氢荧光素分析试剂
批准号：
3876470
负责人：
A BROSSI
金额：
$0.0万
依托单位：
NATIONAL INSTITUTE OF DIABETES AND DIGESTIVE AND KIDNEY DISEASES
依托单位国家：
美国
项目类别：
财政年份：
--
资助国家：
美国
项目状态：
未结题
起止时间：
至
来源：
https://reporter.nih.gov/project-details/3876470
关键词：
alcohols amines catalyst chemical reaction fluoresceins reagent /indicator

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英文摘要
Ethers and acetates of dihydrofluorescein have been developed as analytical reagents. The dibenzylether of dihydrofluorescein seems particularly useful for derivatizing amines and alcohols. Reduction of dihydrofluoresceines in acetic anhydride over Pd(OH)2 catalyst converts the carboxy group into a methyl group, reminiscent of the Rosenmund reduction of acyl chlorides to aldehydes.
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