Carbon-rich Networks and Materials Based on Polyacetylenic Benzenoid Aromatics

本研究的重点是制备和表征 基于聚炔苯型芳族化合物的富碳网络。 两 将构建低聚物亚结构和聚合物， 表征了 目标系统包括石墨二炔、石墨炔和石墨烯。 三炔大环 有了这个奖项，合成有机 该计划支持迈克尔·M·博士的研究。海莉 俄勒冈州大学化学系。 海莉医生会 他的工作重点是制备密集交联的富碳 基于聚炔属苯型聚芳族化合物的固体。 这些聚合物 网络有可能具有适合用作 核发电机、燃气涡轮机用先进结构材料 发动机、高性能热力发动机、热交换器、切削工具， 玻璃碳电极和航空航天应用。

The focus of this research is the preparation and characterization of carbon-rich networks based on polyacetylenic benzenoid aromatics. Both oligomeric substructures and polymers will be constructed and characterized. Target systems include graphdiyne, graphyne and triacetylenic macrocycles. With this award, the Synthetic Organic Program is supporting the research of Dr. Michael M. Haley of the Department of Chemistry at the University of Oregon. Dr. Haley will focus his work on the preparation of densely cross-linked carbon-rich solids based on polyacetylenic benzenoid polyaromatics. These polymeric networks have the potential for having properties amenable to use as advanced structural materials for nuclear power generators, gas turbine engines, high performance heat engines, heat exchangers, cutting tools, glassy carbon electrodes, and aerospace applications.