Carbon-rich Networks and Materials Based on Polyacetylenic Benzenoid Aromatics

本论文的研究重点是基于聚乙烯苯基芳烃的富碳网络的制备和表征。低聚物亚结构和聚合物都将被构建和表征。目标系统包括石墨二炔、三乙炔和三乙炔大环。通过这一奖项，合成有机计划支持了俄勒冈大学化学系的迈克尔·M·黑利博士的研究。黑利博士将把他的工作重点放在以聚乙酰基苯基多芳烃为基础的高密度交联富碳固体的制备上。这些聚合物网络具有作为先进结构材料的潜力，可用于核电发电机、燃气轮机发动机、高性能热机、热交换器、切割工具、玻碳电极和航空航天应用。

The focus of this research is the preparation and characterization of carbon-rich networks based on polyacetylenic benzenoid aromatics. Both oligomeric substructures and polymers will be constructed and characterized. Target systems include graphdiyne, graphyne and triacetylenic macrocycles. With this award, the Synthetic Organic Program is supporting the research of Dr. Michael M. Haley of the Department of Chemistry at the University of Oregon. Dr. Haley will focus his work on the preparation of densely cross-linked carbon-rich solids based on polyacetylenic benzenoid polyaromatics. These polymeric networks have the potential for having properties amenable to use as advanced structural materials for nuclear power generators, gas turbine engines, high performance heat engines, heat exchangers, cutting tools, glassy carbon electrodes, and aerospace applications.